Report for: Tetraarylborate polymer networks as single-ion conducting solid electrolytes

Title	Tetraarylborate polymer networks as single-ion conducting solid electrolytes
Published in	Chemical Science, January 2015
DOI	10.1039/c5sc02052b
Pubmed ID	28757947
Authors	Jeffrey F. Van Humbeck, Michael L. Aubrey, Alaaeddin Alsbaiee, Rob Ameloot, Geoffrey W. Coates, William R. Dichtel, Jeffrey R. Long
Abstract	A new family of solid polymer electrolytes based upon anionic tetrakis(phenyl)borate tetrahedral nodes and linear bis-alkyne linkers is reported. Sonogashira polymerizations using tetrakis(4-iodophenyl)borate, tetrakis(4-iodo-2,3,5,6-tetrafluorophenyl)borate and tetrakis(4-bromo-2,3,5,6-tetrafluorophenyl)borate delivered highly cross-linked polymer networks with both 1,4-diethynylbeznene and a tri(ethylene glycol) substituted derivative. Promising initial conductivity metrics have been observed, including high room temperature conductivities (up to 2.7 × 10(-4) S cm(-1)), moderate activation energies (0.25-0.28 eV), and high lithium ion transport numbers (up to tLi(+) = 0.93). Initial investigations into the effects of important materials parameters such as bulk morphology, porosity, fluorination, and other chemical modification, provide starting design parameters for further development of this new class of solid electrolytes.

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Mendeley readers

The data shown below were compiled from readership statistics for 106 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country	Count	As %
Unknown	106	100%

Demographic breakdown

Readers by professional status	Count	As %
Student > Ph. D. Student	31	29%
Researcher	19	18%
Student > Master	8	8%
Student > Bachelor	6	6%
Professor	5	5%
Other	14	13%
Unknown	23	22%

Readers by discipline	Count	As %
Chemistry	58	55%
Chemical Engineering	10	9%
Materials Science	7	7%
Energy	3	3%
Engineering	2	2%
Other	3	3%
Unknown	23	22%

Attention Score in Context

This research output has an Altmetric Attention Score of 6. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 29 November 2022.

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#4,804,273

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Outputs from Chemical Science

#2,879

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#68,325

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Outputs of similar age from Chemical Science

#153

of 493 outputs

Altmetric has tracked 23,206,358 research outputs across all sources so far. Compared to these this one has done well and is in the 76th percentile: it's in the top 25% of all research outputs ever tracked by Altmetric.

So far Altmetric has tracked 7,984 research outputs from this source. They typically receive more attention than average, with a mean Attention Score of 7.7. This one has gotten more attention than average, scoring higher than 62% of its peers.

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Tetraarylborate polymer networks as single-ion conducting solid electrolytes

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