| Title |
Tetraarylborate polymer networks as single-ion conducting solid electrolytes
|
|---|---|
| Published in |
Chemical Science, January 2015
|
| DOI | 10.1039/c5sc02052b |
| Pubmed ID | |
| Authors |
Jeffrey F. Van Humbeck, Michael L. Aubrey, Alaaeddin Alsbaiee, Rob Ameloot, Geoffrey W. Coates, William R. Dichtel, Jeffrey R. Long |
| Abstract |
A new family of solid polymer electrolytes based upon anionic tetrakis(phenyl)borate tetrahedral nodes and linear bis-alkyne linkers is reported. Sonogashira polymerizations using tetrakis(4-iodophenyl)borate, tetrakis(4-iodo-2,3,5,6-tetrafluorophenyl)borate and tetrakis(4-bromo-2,3,5,6-tetrafluorophenyl)borate delivered highly cross-linked polymer networks with both 1,4-diethynylbeznene and a tri(ethylene glycol) substituted derivative. Promising initial conductivity metrics have been observed, including high room temperature conductivities (up to 2.7 × 10(-4) S cm(-1)), moderate activation energies (0.25-0.28 eV), and high lithium ion transport numbers (up to tLi(+) = 0.93). Initial investigations into the effects of important materials parameters such as bulk morphology, porosity, fluorination, and other chemical modification, provide starting design parameters for further development of this new class of solid electrolytes. |
Mendeley readers
The data shown below were compiled from readership statistics for 111 Mendeley readers of this research output. Click here to see the associated Mendeley record.
Geographical breakdown
| Country | Count | As % |
|---|---|---|
| Unknown | 111 | 100% |
Demographic breakdown
| Readers by professional status | Count | As % |
|---|---|---|
| Student > Ph. D. Student | 32 | 29% |
| Researcher | 21 | 19% |
| Student > Master | 8 | 7% |
| Student > Bachelor | 6 | 5% |
| Other | 5 | 5% |
| Other | 16 | 14% |
| Unknown | 23 | 21% |
| Readers by discipline | Count | As % |
|---|---|---|
| Chemistry | 59 | 53% |
| Chemical Engineering | 11 | 10% |
| Materials Science | 8 | 7% |
| Energy | 3 | 3% |
| Engineering | 2 | 2% |
| Other | 4 | 4% |
| Unknown | 24 | 22% |
Attention Score in Context
This research output has an Altmetric Attention Score of 6. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 29 November 2022.
All research outputs
#4,904,508
of 23,577,761 outputs
Outputs from Chemical Science
#2,953
of 8,188 outputs
Outputs of similar age
#68,902
of 356,684 outputs
Outputs of similar age from Chemical Science
#153
of 496 outputs
Altmetric has tracked 23,577,761 research outputs across all sources so far. Compared to these this one has done well and is in the 76th percentile: it's in the top 25% of all research outputs ever tracked by Altmetric.
So far Altmetric has tracked 8,188 research outputs from this source. They typically receive more attention than average, with a mean Attention Score of 7.8. This one has gotten more attention than average, scoring higher than 62% of its peers.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 356,684 tracked outputs that were published within six weeks on either side of this one in any source. This one has done well, scoring higher than 79% of its contemporaries.
We're also able to compare this research output to 496 others from the same source and published within six weeks on either side of this one. This one has gotten more attention than average, scoring higher than 65% of its contemporaries.